29 juin-1 juil. 2022 Lyon (France)
Accurate Einstein coefficients for electric dipole transitions in the first negative band of N2+
Alexander Alijah  1@  , Olfa Ferchichi  1, 2@  , Najoua Derbel  2@  , Philippe Rousselot  3@  
1 : GSMA
Centre national de la recherche scientifique (CNRS) Université de Reims Champagne-Ardenne (Urca)
2 : Laboratoire de Spectroscopie Atomique, Moléculaire et Applications
3 : UTINAM / OSU THETA
UBFC, Univ Bourgogne Franche-Comte, F- 25000 Besancon, France, CNRS : UMR6213

Context. The N2+ fluorescence spectrum of comet C/2016 R2 is modelled by Rousselot and coworkers (A&A in press). That work relies on accurate Einstein coefficients for electric dipole transitions between the B 2Σu+ and X 2Σg+ electronic states of N2+ .
Aims. These coefficients are provided in the present paper.
Methods. The potential energy curves and transition dipole moments were computed at a high level of ab initio theory and include
relativistic corrections. Rovibrational wavefunctions were then obtained without assuming separability of vibrational and rotational motions.
Results. Vibrationally and rotationally resolved Einstein coefficients are presented in a convenient three-parameter functional form
for three isotopologues. A possible explanation is given for the large variation in the experimental radiative lifetimes.


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